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Synthesis of a new polymer — polycyclopentylenevinylene bearing ge‐containing group
Author(s) -
Finkelshtein Eugene Sh.,
Portnykh Elena B.,
Ushakov Nikolai V.,
Gringolts Maria L.,
Yampolsky Yury P.
Publication year - 1997
Publication title -
macromolecular chemistry and physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.57
H-Index - 112
eISSN - 1521-3935
pISSN - 1022-1352
DOI - 10.1002/macp.1997.021980412
Subject(s) - bearing (navigation) , polymer chemistry , group (periodic table) , polymer science , polymer , materials science , chemistry , organic chemistry , composite material , computer science , artificial intelligence
A new polymer, poly[5‐(trimethylgermylmethyl)‐1,3‐cyclopentylenevinylene], was synthesized via ROMP of 5‐(trimethylgermylmethyl)‐2‐norbornene in the presence of RuCl 3 · 3H 2 O, RuCl 3 (PPh 3 ) 3 and RuCl 2 (PPh 3 ) 3 catalysts. The structure of the synthesized polymer was determined on the basis of IR, 1 H NMR and 13 C NMR spectra. The gas transport properties for this polymer have been studied.