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Formation of supramolecular aggregates by hydrogen bonding based on bispyrimidine and bisbarbituric acid
Author(s) -
Wang Zhiqiang,
Wang Liyan,
Zhang Xi,
Shen Jiacong,
Denzinger Steffen,
Ringsdorf Helmut
Publication year - 1997
Publication title -
macromolecular chemistry and physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.57
H-Index - 112
eISSN - 1521-3935
pISSN - 1022-1352
DOI - 10.1002/macp.1997.021980229
Subject(s) - supramolecular chemistry , hydrogen bond , polymer chemistry , supramolecular polymers , chemistry , polymer science , materials science , organic chemistry , molecule
Hydrogen bonds between bispyrimidine and bisbarbituric acid in equal molar ratio can lead to the formation of supramolecular aggregates. This is established by TEM, IR and DSC measurements. Additionally, WAXS pattern showed that the aggregate is of laminar structure. Both the hydrolysis of this system and termination of the aggregate's growth were studied.