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Synthesis and characterization of monomethacrylate‐functionalized self‐organizing crown ether compounds
Author(s) -
Percec Virgil,
Zipp Gabriela,
Johansson Gary,
Beginn Uwe,
Möller Martin
Publication year - 1997
Publication title -
macromolecular chemistry and physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.57
H-Index - 112
eISSN - 1521-3935
pISSN - 1022-1352
DOI - 10.1002/macp.1997.021980204
Subject(s) - trifluoromethanesulfonate , differential scanning calorimetry , polymer chemistry , crown ether , hydroxymethyl , ether , methacrylate , characterization (materials science) , chemistry , copolymer , materials science , organic chemistry , polymer , nanotechnology , ion , catalysis , thermodynamics , physics
Synthesis and characterization of methacrylate‐monofunctionalized crown ether compounds based on derivatives of 2‐hydroxymethyl‐1,4,7,10,13‐pentaoxacyclopentadecane and 4′‐hydroxymethyl‐1,4,7,10,13‐pentaoxabenzocyclopentadecane is described. By differential scanning calorimetry (DSC) and thermooptical analysis (TOA) it is shown that the synthesized compounds and their sodium triflate complexes exhibit columnar mesophases.