Synthèse de l'acide 2‐acrylamido 2‐méthylpropanoïque et copolymérisation avec l'acrylamide | Zendy

Camail Michel | Zendy; Margaillan André | Zendy; Thuret Sandrine | Zendy; Vernet JeanLouis | Zendy

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Synthèse de l'acide 2‐acrylamido 2‐méthylpropanoïque et copolymérisation avec l'acrylamide

Author(s) -

Camail Michel,

Margaillan André,

Thuret Sandrine,

Vernet JeanLouis

Publication year - 1996

Publication title -

macromolecular chemistry and physics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.57

H-Index - 112

eISSN - 1521-3935

pISSN - 1022-1352

DOI - 10.1002/macp.1996.021970821

Subject(s) - copolymer , monomer , polymer chemistry , acrylamide , chemistry , reactivity (psychology) , acrylic acid , polymer , organic chemistry , medicine , alternative medicine , pathology

The synthesis of 2‐acrylamido‐2‐methylpropanoic acid (2A2MPA) was carried out starting from 2‐methylpropanoic acid. Copolymerizations of the 2A2MPA salt (2A2MPANa, monomer A) with acrylamide (AM, monomer B) were investigated using K 2 S 2 O 8 as initiator. They were terminated before reaching 15% conversion. A range of feed compositions was selected (2A2MPANa increasing from 10 to 100 mol‐%) and the compositions of the copolymers obtained were assessed through 13 C NMR. The reactivity ratios for the couple A, B were determined as r A = 0,76 and r B = 1,06. One additional copolymerization was allowed to reach 100% conversion, and the final copolymer showed interesting drag reduction properties.

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