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Rare earth metal initiated polymerizations of polar and nonpolar monomers to give high molecular weight polymers with extremely narrow molecular weight distribution
Author(s) -
Yasuda Hajime,
Ihara Eiji
Publication year - 1995
Publication title -
macromolecular chemistry and physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.57
H-Index - 112
eISSN - 1521-3935
pISSN - 1022-1352
DOI - 10.1002/macp.1995.021960802
Subject(s) - molar mass distribution , polymer chemistry , monomer , polymer , polar , metal , rare earth , polymerization , chemistry , materials science , polymer science , organic chemistry , mineralogy , physics , astronomy
Organolanthanide (III) initiated polymerizations of alkyl methacrylates and alkyl acrylates proceed in a living fashion and yield high molecular weight polymers with extremely narrow molecular weight distribution at high conversion. Random and block copolymerizations of alkyl acrylates are carried out successfully to give almost “monodisperse” polymers. Rare earth metal initiated polymerizations of lactones such as ε‐caprolactone and δ‐valerolactone produce again high molecular weight polymers with narrow molecular weight distribution. Bulky divalent and trivalent rare earth metal complexes catalyze the living polymerization of ethylene and α‐olefins and the Sm (OR) 3 /AIR 3 H 2 O initiator system catalyzes the polymerization of propylene oxide to give polymers with narrow molecular weight distribution.