Synthèse d'un monomère styrénique à substituant phosphonique. Instabilité de la forme diacide et polymérisation | Zendy

Boutevin Bernard | Zendy; Hamoui Bachar | Zendy; Bessière Jeanmarie M. | Zendy

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Synthèse d'un monomère styrénique à substituant phosphonique. Instabilité de la forme diacide et polymérisation

Author(s) -

Boutevin Bernard,

Hamoui Bachar,

Bessière Jeanmarie M.

Publication year - 1995

Publication title -

macromolecular chemistry and physics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.57

H-Index - 112

eISSN - 1521-3935

pISSN - 1022-1352

DOI - 10.1002/macp.1995.021960606

Subject(s) - copolymer , polymer chemistry , chemistry , polymerization , salt (chemistry) , silylation , radical polymerization , polymer , organic chemistry , catalysis

p ‐Vinylbenzyphonic acid was prepared by means of the Arbuzov reaction between triethyl phosphite and p ‐chloromethylstyrene followed by silylation with bromotrimethylsilane and methanolysis. The product, which is readily cross‐linked, is stabilized as dicyclohexycylammonium salt. Radical‐initiated polymerization occurs readily; homo‐ and copolymers found are slowly cross‐linked upon releasing dicyclohexylamine.

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