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Kinetics of the chemical polymerization of pyrrole by potassium hexacyanoferrate(III)
Author(s) -
Stanković Rade,
Laninović Verica,
Stanković Slavka,
Jovanović Slobodan,
Vojnović Milan
Publication year - 1995
Publication title -
macromolecular chemistry and physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.57
H-Index - 112
eISSN - 1521-3935
pISSN - 1022-1352
DOI - 10.1002/macp.1995.021960312
Subject(s) - polymerization , pyrrole , chemistry , kinetics , potassium , polymer chemistry , reaction rate constant , chemical kinetics , order of reaction , organic chemistry , polymer , physics , quantum mechanics
The kinetics of the chemical polymerization of pyrrole by potassium hexacyanoferrate(III) in water at 0°C was studied. The order of the reaction with respect to both pyrrole and potassium hexacyanoferrate(III) was determined to be 1 and 2,6, respectively. The rate constant k of the polymerization reaction was found to be 2,25 · 10 −4 (dm 3 · mol −1 ) 2,6 · s −1 .