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Polymer‐bound porphyrins and their precursors, 11 . Syntheses and polymerization of methacryloyloxy and 2,4‐hexadienoyloxy derivatives of porphyrins and phthalocyanines
Author(s) -
Eichhorn Holger,
Sturm Michael,
Wöhrle Dieter
Publication year - 1995
Publication title -
macromolecular chemistry and physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.57
H-Index - 112
eISSN - 1521-3935
pISSN - 1022-1352
DOI - 10.1002/macp.1995.021960107
Subject(s) - copolymer , chemistry , polymer chemistry , styrene , polymer , polymerization , porphyrin , photochemistry , organic chemistry
Abstract The syntheses of tetraphenylporphyrins 1b, d, e containing four methacryloyloxy or 2,4‐hexadienoyloxy substituents and phthalocyanines 2b, d containing four methacryloyloxy substituents are described. Copolymerizations with styrene in solution were investigated in detail, and the compositions and molecular weights of the copolymers were determined. In addition, homopolymerizations in solution were carried out. After coating on quartz or KBr plates, the thermal and photochemically induced homopolymerizations were investigated fundamentally.