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Amino acids attached to poly(alkylene phosphate)s, 1. Synthesis
Author(s) -
Kaluzynski Krzysztof,
Penczek Stanislaw
Publication year - 1994
Publication title -
macromolecular chemistry and physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.57
H-Index - 112
eISSN - 1521-3935
pISSN - 1022-1352
DOI - 10.1002/macp.1994.021951211
Subject(s) - amino acid , hydrolysis , trimethylsilyl , phosphate , chemistry , polymer , polymer chemistry , organic chemistry , biochemistry
The synthesis of poly(alkylene phosphate)s with attached amino acids was elaborated. Two methods of coupling through P—NH bond were used. They were based on the direct reaction of amino acid esters or N , O ‐bis(trimethylsilyl) substituted amino acids with poly(alkylene chlorophosphate)s. The assumed microstructure of the resulting polymers was confirmed by analysis of the 1 H, 13 C and 31 P NMR spectra. Preliminary data on the hydrolytic stability of amino acids modified poly(alkylene phosphate)s are also given.