Metathesis polymerization of  endo ‐5‐ and  exo ‐5‐chloromethylbicyclo[2.2.1]hept‐2‐ene and of 5,5‐bis(chloromethyl)bicyclo[2.2.1]hept‐2‐ene; microstructure of the polymers | Zendy

Ivin Kenneth J. | Zendy; Lam LukMui | Zendy; Rooney John J. | Zendy

Premium

Metathesis polymerization of endo ‐5‐ and exo ‐5‐chloromethylbicyclo[2.2.1]hept‐2‐ene and of 5,5‐bis(chloromethyl)bicyclo[2.2.1]hept‐2‐ene; microstructure of the polymers

Author(s) -

Ivin Kenneth J.,

Lam LukMui,

Rooney John J.

Publication year - 1994

Publication title -

macromolecular chemistry and physics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.57

H-Index - 112

eISSN - 1521-3935

pISSN - 1022-1352

DOI - 10.1002/macp.1994.021950921

Subject(s) - ene reaction , metathesis , monomer , polymer , polymerization , polymer chemistry , chemistry , yield (engineering) , ring opening metathesis polymerisation , double bond , materials science , stereochemistry , organic chemistry , metallurgy

The three title monomers were polymerized using a variety of Ru‐, Ir‐, Mo‐, W‐ and Re‐based metathesis catalyst systems to yield polymers having a wide range of cis double bond contents in each case. The 13 C NMR spectra of the polymers were interpreted in terms of cis/trans , head/tail and m/r microstructures. No head‐tail bias was observed in any of the polymers.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research