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Zur kinetik der copolymerisation von methacrylaten mit entkoppelter seitengruppe
Author(s) -
Rübner Joachim,
Geßner Uwe,
Rodekirch Gerhard,
Ruhmann Ralf
Publication year - 1994
Publication title -
macromolecular chemistry and physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.57
H-Index - 112
eISSN - 1521-3935
pISSN - 1022-1352
DOI - 10.1002/macp.1994.021950308
Subject(s) - mesogen , copolymer , polymer chemistry , monomer , methacrylate , materials science , chemistry , polymer , liquid crystalline , organic chemistry
The copolymerization behavior of methacrylate monomers with several decoupled side groups was studied depending on the structure of the linked mesogen. Some units (NN, CONH) in the mesogen influence the copolymerization reaction in spite of the strong decoupling by a C 6 ‐spacer group and lead to retarding effects and to the preferred insertion of monomers with weaker mesogenic interactions. The liquid‐crystalline behaviour of the copolymers was not affected due to the relatively small differences in the copolymerization parameters.