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Improvement of the corrosion characteristics of 1.4713 ferritic steel in 0.1 M sulfuric acid by heat treatment and Al 2 O 3 –TiO 2 coating
Author(s) -
Stevanović Dimitrije,
Dimitrijević Stevan P.,
Kamberović Željko,
Parežanin Vladimir,
Dimitrijević Silvana B.
Publication year - 2021
Publication title -
materials and corrosion
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.487
H-Index - 55
eISSN - 1521-4176
pISSN - 0947-5117
DOI - 10.1002/maco.202012197
Subject(s) - tafel equation , corrosion , materials science , dielectric spectroscopy , sulfuric acid , coating , metallurgy , polarization (electrochemistry) , electrochemistry , composite material , electrode , chemistry
Abstract This study addresses the influence of heat treatment and alumina coating on the corrosion of EN 1.4713 steel in 0.1 mol dm −3 sulfuric acid. The corrosion characteristics of three different samples are examined using the open circuit potential measurements, Tafel extrapolation, linear polarization resistance, weight‐loss method, and electrochemical impedance spectroscopy. The results showed that the application of the weight‐loss method yielded similar values to the electrochemical method in the first 24 h. A decrease in corrosion rate, in a similar manner, was observed for all three samples. The largest deacceleration was obtained for the alumina/titania‐coated sample. It was obtained that the heat treatment significantly increased the corrosion resistance, but only in the first 24 h. The alumina/titania coating decreases the corrosion rate by approximately 30 times at the beginning of the corrosion exposure and by nearly 300 times after 240 h. This coating could have a significant influence on construction design, which uses ferritic stainless steel as the material.