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Effect of different aging processes on the corrosion behavior of new Al–Cu–Li–Zr–Sc alloys
Author(s) -
Peng Zhuowei,
Pan Qinglin,
Cai Shan,
Li Jinfeng,
Liang Wenjie
Publication year - 2019
Publication title -
materials and corrosion
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.487
H-Index - 55
eISSN - 1521-4176
pISSN - 0947-5117
DOI - 10.1002/maco.201911191
Subject(s) - corrosion , intergranular corrosion , materials science , grain boundary , alloy , metallurgy , precipitation , dissolution , phase (matter) , microstructure , chemical engineering , chemistry , physics , organic chemistry , meteorology , engineering
The intergranular corrosion and exfoliation corrosion behaviors of Al–Cu–Li–Zr–Sc alloys under different aging effects, such as single‐stage aging, strain aging, and double‐stage aging, were studied. Among the three aging treatments, single‐stage aging resulted in the best resistance to corrosion, followed by double‐stage aging; strain aging resulted in the worst corrosion resistance. A 3.5% precooling strain could increase the dislocation density, which promoted the precipitation of corrosion‐prone T 1 phase and increased the corrosion driving force of the alloy. Double‐stage aging made the precipitated T 1 phases finer and more uniform and reduced the number of equilibrium phases at grain boundaries, thus improving the corrosion properties of the alloy. The corrosion susceptibility of the alloy was attributed to the T 1 phase and precipitate‐free zone (PFZ), and the underlying corrosion mechanism was revealed as preferential dissolution of the equilibrium phase at grain boundaries and its surrounding distortion zone, followed by expansion of the PFZ along the grain boundaries, resulting in the development of corrosion from the grain boundaries to the intragranular regions.