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Experimental and computational evaluation of illicium verum as a novel eco‐friendly corrosion inhibitor for aluminium
Author(s) -
Ladha D. G.,
Shah N. K.,
Ghelichkhah Z.,
Obot I. B.,
Khorrami Dehkharghani F.,
Yao J.Z.,
Macdonald D. D.
Publication year - 2018
Publication title -
materials and corrosion
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.487
H-Index - 55
eISSN - 1521-4176
pISSN - 0947-5117
DOI - 10.1002/maco.201709581
Subject(s) - corrosion inhibitor , aluminium , dielectric spectroscopy , corrosion , gravimetric analysis , hydrochloric acid , physisorption , adsorption , chemistry , materials science , metal , chemical engineering , analytical chemistry (journal) , electrochemistry , inorganic chemistry , chromatography , organic chemistry , electrode , engineering
Illicium verum extract is investigated as a corrosion inhibitor of aluminium in the presence of an acid medium using gravimetric and impedance techniques. The gravimetric results reveal that the adsorption of inhibitor on the metal surface is physisorption. The impedance measurements are used to interpret the electrochemical process occurring at the interface of aluminium and corrosive medium. The surface characteristics of aluminium are evaluated using scanning electron microscopy‐energy dispersive X‐ray spectroscopy. The percentage composition of chemical constituents present in the extract is obtained using gas chromatography‐mass spectrometry and E‐anethole is found to be the main chemical component. The interaction between the chemical constituents or inhibitor molecules and the metal surface are evaluated using Monte Carlo simulation. The determination of electron density on the inhibitor molecules is performed using density functional theory. The results from this respective study demonstrate good inhibitive properties of the illicium verum extract towards the corrosion of aluminium in concentrated hydrochloric acid solution.