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Novel zinc‐rich epoxy paint coatings with hydrated alumina and carbon nanotubes supported polypyrrole for corrosion protection of low carbon steel: Part II: Corrosion prevention behavior of the hybrid paint coatings
Author(s) -
Gergely A.,
Pászti Z.,
Bertóti I.,
Török T.,
Mihály J.,
Kálmán E.
Publication year - 2013
Publication title -
materials and corrosion
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.487
H-Index - 55
eISSN - 1521-4176
pISSN - 0947-5117
DOI - 10.1002/maco.201206707
Subject(s) - materials science , dielectric spectroscopy , corrosion , carbon nanotube , galvanic cell , zinc , x ray photoelectron spectroscopy , polypyrrole , carbon steel , hybrid material , composite material , epoxy , galvanic anode , galvanic corrosion , salt spray test , chemical engineering , electrochemistry , metallurgy , nanotechnology , cathodic protection , electrode , polymer , chemistry , engineering , polymerization
Utilization of various types of multi‐walled carbon nanotubes (MWCNTs) in zinc‐rich paints (ZRPs) is presented addressing percolation and porosity related phenomena of traditional ZRPs. Hybrid paint coatings were formulated with 3.21 wt% polypyrrole (PPy) deposited alumina‐MWCNT inhibitor particles (PDAMIPs) and 70 wt% zinc contents. Corrosion protection behavior of the hybrid coatings was investigated by electrochemical impedance spectroscopy (EIS), glow‐discharge optical emission spectroscopy (GD OES), X‐ray photoelectron spectroscopy (XPS), and FT‐Raman spectroscopy. Immersion and salt‐spray chamber tests gave evidence of improved galvanic protection and barrier nature of the hybrid coatings over the conventional ZRPs, whereas inhibited zinc corrosion and ignorable steel corrosion took place besides lower degradation of the binder. Zinc‐rich hybrid paints with either high relative amount of polyelectrolyte‐modified or low proportion of functionalized MWCNTs afforded enhanced corrosion prevention. This result is partly attributed to the nanotube volume fractions around the threshold of infinite cluster formation contributing to electrical percolation and galvanic action of the hybrids. Experimental results are discussed in a broader context on the basis of structure related findings of the PDAMIPs (described in Part I) and in the light of recent literature data. From the newly developed inhibitor particles, some of them are respected as worthy additives for application in hybrid coatings featuring high performance corrosion prevention functionality.