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Dynamic electrochemical impedance spectroscopy and polarization studies to evaluate the inhibition effect of benzotriazole on copper‐manganese‐aluminium alloy in artificial seawater
Author(s) -
Gerengi H.,
Slepski P.,
Bereket G.
Publication year - 2013
Publication title -
materials and corrosion
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.487
H-Index - 55
eISSN - 1521-4176
pISSN - 0947-5117
DOI - 10.1002/maco.201206565
Subject(s) - tafel equation , benzotriazole , dielectric spectroscopy , artificial seawater , copper , seawater , corrosion , manganese , aluminium , materials science , alloy , polarization (electrochemistry) , electrochemistry , metallurgy , analytical chemistry (journal) , chemistry , chromatography , electrode , oceanography , geology
The effect of benzotriazole (BTA) on the corrosion of a new type copper‐manganese‐aluminium (CMA) alloy in artificial seawater was investigated using dynamic electrochemical impedance spectroscopy (DEIS), linear polarization resistance, and Tafel extrapolation methods. Measurement results obtained from those three methods showed that corrosion rates decreased while BTA concentration increased. This clearly indicates that BTA inhibits the corrosion rate of CMA in artificial seawater. Although there are consistent results obtained from all these three methods, the results of the percent inhibition efficiency, IE (%), values obtained from DEIS method should be calculated from the charge transfer resistance ( R ct ) values obtained after 5 h.