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Reactivity of the surface of zirconium during pickling in nitric‐hydrofluoric acid
Author(s) -
Hlawka F.,
Sutter E. M. M.
Publication year - 1991
Publication title -
materials and corrosion
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.487
H-Index - 55
eISSN - 1521-4176
pISSN - 0947-5117
DOI - 10.1002/maco.19910420807
Subject(s) - pickling , hydrofluoric acid , nitric acid , dissolution , zirconium , inorganic chemistry , chemistry , hydrogen peroxide , oxide , metal , materials science , organic chemistry
The behaviour of zirconium in hydrofluoric‐nitric acid pickling solutions has been studied using electrochemical methods, X‐ray diffraction and Raman spectrometry. During a pickling experiment the depletion of the solutions could be correlated with the consumption of hydrofluoric acid to form metal oxo‐ or oxofluorocomplexes. The role of nitric acid added to the hydrofluoric acid for pickling has been discussed after replacing it by other strong acids or by hydrogen peroxide. It appears that the zirconium dissolution rate only depends on the hydrofluoric acid concentration, but that the properties of the oxide film are determined by the nature of the strong acid added to HF; it can be assumed that metal dissolution occurs through the oxide film and that ionic diffusion through the film is a rate determining step.