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The corrosion behavior of stainless steels and copper alloys exposed to natural seawater
Author(s) -
Little Brenda J.,
Mansfeld Florian B.
Publication year - 1991
Publication title -
materials and corrosion
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.487
H-Index - 55
eISSN - 1521-4176
pISSN - 0947-5117
DOI - 10.1002/maco.19910420702
Subject(s) - copper , corrosion , materials science , metallurgy , titanium , cathodic protection , seawater , alloy , electrochemistry , metal , titanium alloy , artificial seawater , electrode , chemistry , oceanography , geology
The corrosion behavior of stainless steels, titanium and copper alloys exposed to flowing Pacific Ocean water was characterized using surface analytical and electrochemical techniques. Biofilm formation on stainless steels and titanium resulted in thin films of bacteria and diatoms that did not cause significant changes of the corrosion potential (E corr ) or surface properties. Rotating cylinder experiments indicated that both E corr and corrosion rates for stainless steels and titanium were independent of mass transport. Four surface layers were identified on copper‐containing materials: substratum metal; an inorganic chloride corrosion layer that contained alloying elements; a biofilm; and crystalline, spherical phosphate‐rich deposits. All copper surfaces were colonized by bacteria independent of alloy composition. The complexity of the impedance spectra for copper‐containing materials was attributed to formation of surface layers and contributions of charge transfer and mass transport controlled reactions mediated by the layers. Both anodic and cathodic reactions for copper‐based materials were affected by mass transport.