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Corrosion in solar heating systems. I. Copper behaviour in water/glycol solutions
Author(s) -
Monticelli C.,
Brunoro G.,
Trabanelli F. G.,
Frignani A.
Publication year - 1986
Publication title -
materials and corrosion
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.487
H-Index - 55
eISSN - 1521-4176
pISSN - 0947-5117
DOI - 10.1002/maco.19860370902
Subject(s) - copper , ethylene glycol , corrosion , chloride , materials science , galvanic cell , pitting corrosion , aluminium , erosion corrosion of copper water tubes , electrolyte , alloy , metallurgy , electrochemistry , inorganic chemistry , chemistry , electrode , organic chemistry
A research programme has been developed in order to investigate the corrosion behaviour of metallic materials commonly used in solar heating systems. This paper presents the results of an experimental study on copper corrosion resistance in ethylene and propylene glycol/water solutions (1:1 by volume) constituting the most common bases of heat transfer fluids. Long time gravimetric tests were carried out on electrolytic copper at 80°C, even in glycol/water solutions previously degraded at their boiling temperature or polluted with 200 ppm chlorides. Chemical compositions, semiconducting properties and morphological characteristics of all surface products were investigated by X‐ray diffraction analysis, pulse photopotential technique and SEM observations, respectively. Heat transfer effects on copper corrosion and copper/6351 aluminium alloy couple efficiency were evaluated by electrochemical tests. The following results were obtained: – Ethylene and propylene glycol/water solutions are low corrosive media. Nevertheless, chloride pollution and/or high temperature degradation of glycols markedly increase their aggressivity. Under all the experimental conditions, copper corrosion rates are higher in ethylene than propylene glycol solutions. – In chloride‐free solutions, heat transfer stimulates the cathodic reaction of the copper corrosion process. – Galvanic contact between copper and aluminium alloy always causes pitting corrosion on aluminium electrodes. The severity of the pitting attack is enhanced by the presence of heat transfer conditions on copper and/or chloride ions in the solutions, particularly in ethylene glycol.