Kinetics of the formation, decomposition, and disproportionation reactions of  N ‐chlorobutylamines | Zendy

Antelo Juan M. | Zendy; Arce Florencio | Zendy; Castro Marí C. | Zendy; Crugeiras Juan | Zendy; PérezMoure Juan C. | Zendy; Rodríguez Pilar | Zendy

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Kinetics of the formation, decomposition, and disproportionation reactions of N ‐chlorobutylamines

Author(s) -

Antelo Juan M.,

Arce Florencio,

Castro Marí C.,

Crugeiras Juan,

PérezMoure Juan C.,

Rodríguez Pilar

Publication year - 1995

Publication title -

international journal of chemical kinetics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.341

H-Index - 68

eISSN - 1097-4601

pISSN - 0538-8066

DOI - 10.1002/kin.550270709

Subject(s) - chemistry , disproportionation , decomposition , kinetics , hypochlorite , aqueous medium , amine gas treating , aqueous solution , chemical decomposition , kinetic energy , medicinal chemistry , organic chemistry , catalysis , physics , quantum mechanics

The formation of N ‐chlorobutylamines is a reaction of order one with respect to hypochlorite and amine, and order −1 with respect to OH − . Kinetic studies show that N ‐chlorobutylamines undergo decomposition in basic aqueous media, and disproportination (with formation of N , N ‐dichloramines) in acidic media, mechanisms are put forward for both these processes. © 1995 John Wiley & Sons, Inc.

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