Comparison of singlet methylene removal rates by group IV hydrides | Zendy

Gutsche Greg J. | Zendy; Lawrance Warren D. | Zendy; Staker Warren S. | Zendy; King Keith D. | Zendy

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Comparison of singlet methylene removal rates by group IV hydrides

Author(s) -

Gutsche Greg J.,

Lawrance Warren D.,

Staker Warren S.,

King Keith D.

Publication year - 1995

Publication title -

international journal of chemical kinetics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.341

H-Index - 68

eISSN - 1097-4601

pISSN - 0538-8066

DOI - 10.1002/kin.550270612

Subject(s) - chemistry , methylene , singlet state , reaction rate constant , germane , flash photolysis , photochemistry , singlet oxygen , laser , silane , photodissociation , methane , analytical chemistry (journal) , medicinal chemistry , organic chemistry , atomic physics , excited state , kinetics , optics , oxygen , silicon , physics , germanium , quantum mechanics

The technique of laser flash photolysis/laser absorption has been used to obtain an absolute removal rate constant of (3.85 ± 0.18) × 10 −10 cm 3 molecule −1 s −1 for singlet methylene, 1 CH 2 (ã 1 A 1 ), with germane (GeH 4 ) at ambient temperature. The removal rate constant is compared with the values for methane (CH 4 ) and silane (SiH 4 ) which have been determined previously. © 1995 John Wiley & Sons, Inc.

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