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A novel correlative relationship among rates of complexation of 1:1 copper(II) diketonates and basicity of the ligand
Author(s) -
Verdú Jesus,
Blanco Carlos A.
Publication year - 1994
Publication title -
international journal of chemical kinetics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.341
H-Index - 68
eISSN - 1097-4601
pISSN - 0538-8066
DOI - 10.1002/kin.550260708
Subject(s) - chemistry , copper , reactivity (psychology) , ligand (biochemistry) , reaction rate constant , kinetic energy , complex formation , inorganic chemistry , kinetics , medicinal chemistry , organic chemistry , receptor , biochemistry , medicine , physics , alternative medicine , pathology , quantum mechanics
An exceptional kinetic behavior on the reactivity of β‐diketones against copper(II) have been found. Some relationship between ligand basicity and unexpected enhancement on the rates of complex formation, which may be useful for predicting rate constants of similar monochelated copper(II) complexes, are established. © 1994 John Wiley & Sons, Inc.