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In situ separation of heterogeneous and homogeneous reaction components in flow experiment
Author(s) -
Orkin V. L.,
Khamaganov V. G.,
Larin I. K.
Publication year - 1993
Publication title -
international journal of chemical kinetics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.341
H-Index - 68
eISSN - 1097-4601
pISSN - 0538-8066
DOI - 10.1002/kin.550250202
Subject(s) - chemistry , homogeneous , in situ , flow (mathematics) , reaction rate constant , phase (matter) , transformation (genetics) , gas phase , thermodynamics , biological system , mechanics , kinetics , organic chemistry , biochemistry , physics , quantum mechanics , biology , gene
A method is suggested for the determination of the character (homogeneous or heterogeneous) of the material transformation in the investigation of gas‐phase reactions under tubular flow conditions. The method provides the estimation of the error in the rate constant of a gas‐phase reaction due to the possible parallel occurrence of a heterogeneous process. © 1993 John Wiley & Sons, Inc.