Nitrenium ions in N‐chloro‐α‐amino acids decomposition? | Zendy

Armesto X. L. | Zendy; Canle L. M. | Zendy; Losada M. | Zendy; Santaballa J. A. | Zendy

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Nitrenium ions in N‐chloro‐α‐amino acids decomposition?

Author(s) -

Armesto X. L.,

Canle L. M.,

Losada M.,

Santaballa J. A.

Publication year - 1993

Publication title -

international journal of chemical kinetics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.341

H-Index - 68

eISSN - 1097-4601

pISSN - 0538-8066

DOI - 10.1002/kin.550250102

Subject(s) - chemistry , decomposition , kinetics , leucine , aqueous solution , amino acid , ion , isoleucine , medicinal chemistry , computational chemistry , stereochemistry , organic chemistry , biochemistry , physics , quantum mechanics

This article deals with the kinetics of decomposition of four isomers: NCl‐(L)‐2‐Aminohexanoic acid, NCl‐(L)‐Leucine, NCl‐(L)‐Isoleucine, and NCl‐(L)‐ tert ‐Leucine, in mild acid and basic aqueous solution. An alternative mechanism for this process which takes place through a nitrenium‐like ion transition state is proposed. This mechanism is in consonance with the experimental data and with those available from the literature. © 1993 John Wiley & Sons, Inc.

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