Kinetics of the  N ‐chlorination of 2‐aminobutyric, 3‐aminobutyric, 3‐aminoisobutyric and 4‐aminobutyric acids in aqueous solution | Zendy

Antelo J. M. | Zendy; Arce F. | Zendy; Pérezmoure J. C. | Zendy

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Kinetics of the N ‐chlorination of 2‐aminobutyric, 3‐aminobutyric, 3‐aminoisobutyric and 4‐aminobutyric acids in aqueous solution

Author(s) -

Antelo J. M.,

Arce F.,

Pérezmoure J. C.

Publication year - 1992

Publication title -

international journal of chemical kinetics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.341

H-Index - 68

eISSN - 1097-4601

pISSN - 0538-8066

DOI - 10.1002/kin.550241207

Subject(s) - chemistry , aminobutyric acid , aqueous solution , kinetics , amino acid , sodium hypochlorite , ion , hypochlorite , medicinal chemistry , inorganic chemistry , chromatography , organic chemistry , biochemistry , physics , receptor , quantum mechanics

We studied the kinetics of the N ‐chlorination of 2‐aminobutyric, 3‐aminoisobutyric, and 4‐aminobutyric acids by sodium hypoclorite in strongly alkaline aqueous solution. As in the case of other amines, the rate of formation of the four N ‐chloroamino acids was proportional to the concentrations of hypochlorite and amino acid, and inversely proportional to the concentration of hydroxyl ions. A reaction mechanism compatible with these results is proposed and discussed. © John Wiley & Sons, Inc.

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