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Shock tube and modeling study of propene pyrolysis
Author(s) -
Hidaka Yoshiaki,
Nakamura Takuji,
Tanaka Hiroya,
Jinno Akinori,
Kawano Hiroyuki,
Higashihara Tetsuo
Publication year - 1992
Publication title -
international journal of chemical kinetics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.341
H-Index - 68
eISSN - 1097-4601
pISSN - 0538-8066
DOI - 10.1002/kin.550240902
Subject(s) - propene , chemistry , shock tube , pyrolysis , shock wave , thermal decomposition , reaction mechanism , kinetic energy , shock (circulatory) , decomposition , analytical chemistry (journal) , absorption (acoustics) , thermodynamics , organic chemistry , catalysis , optics , physics , medicine , quantum mechanics
The thermal decomposition of propene behind reflected shock waves with 1200 < T 5 < 1800 K and 1.6 × 10 −5 < ρ 5 < 2.7 × 10 −5 mol/cm 3 was studied by IR laser kinetic absorption spectroscopy and gas‐chromatographic analysis of reaction products. The present data together with earlier shock tube data were satisfactorily modeled with a 51‐reaction mechanism. As the initial step of the reaction, three channels, C 3 H 6 = CH 3 + C 2 H 3 (1), C 3 H 6 = H + AC 3 H 5 (2), and C 3 H 6 = CH 4 + C 2 H 2 (3), were necessary to interpret all the experimental data. © John Wiley & Sons, Inc.
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