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Kinetics and mechanism of oxidation of hydroxylamine by peroxomonosulphate
Author(s) -
Sharma Madhu,
Prasad D. S. N.,
Gupta K. S.
Publication year - 1992
Publication title -
international journal of chemical kinetics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.341
H-Index - 68
eISSN - 1097-4601
pISSN - 0538-8066
DOI - 10.1002/kin.550240706
Subject(s) - chemistry , kinetics , hydroxylamine , reactivity (psychology) , rate equation , mechanism (biology) , medicinal chemistry , computational chemistry , organic chemistry , medicine , philosophy , physics , alternative medicine , epistemology , pathology , quantum mechanics
The kinetics of the reaction (1) obey the rate law (2) in acetate buffered solutions. A comparison with H 2 O 2 and S 2 O 8 2− shows the reactivity order to be H 2 O 2 < HSO 5 − > S 2 O 8 2− . © John Wiley & Sons, Inc.