Pd(II) complexes of amino alcohols and their reaction with chloramine‐ T : A kinetic study | Zendy

Shukla Anju | Zendy; Gupta Sushma | Zendy; Upadhyay Santosh K. | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Pd(II) complexes of amino alcohols and their reaction with chloramine‐ T : A kinetic study

Author(s) -

Shukla Anju,

Gupta Sushma,

Upadhyay Santosh K.

Publication year - 1991

Publication title -

international journal of chemical kinetics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.341

H-Index - 68

eISSN - 1097-4601

pISSN - 0538-8066

DOI - 10.1002/kin.550230402

Subject(s) - chemistry , chloramine t , triethanolamine , chloramine , perchloric acid , kinetics , kinetic energy , catalysis , medicinal chemistry , chloride , inorganic chemistry , organic chemistry , chlorine , analytical chemistry (journal) , physics , quantum mechanics

The kinetics of reaction of amino alcohols viz. 2‐aminoethanol, 3‐aminopropanol, and triethanolamine with chloramine‐ T have been studied in perchloric acid medium with palladous chloride as catalyst. The formation of {Pd(II)‐(aminoalcohol)} and {Pd(II)‐(aminoalcohol) 2 } complexes and resistance of {Pd(II)‐(aminoalcohol) 2 } complex to react with chloramine‐ T have been observed. A suitable mechanism consistent with the kinetic data is proposed and discussed.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research