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Pd(II) complexes of amino alcohols and their reaction with chloramine‐ T : A kinetic study
Author(s) -
Shukla Anju,
Gupta Sushma,
Upadhyay Santosh K.
Publication year - 1991
Publication title -
international journal of chemical kinetics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.341
H-Index - 68
eISSN - 1097-4601
pISSN - 0538-8066
DOI - 10.1002/kin.550230402
Subject(s) - chemistry , chloramine t , triethanolamine , chloramine , perchloric acid , kinetics , kinetic energy , catalysis , medicinal chemistry , chloride , inorganic chemistry , organic chemistry , chlorine , analytical chemistry (journal) , physics , quantum mechanics
The kinetics of reaction of amino alcohols viz. 2‐aminoethanol, 3‐aminopropanol, and triethanolamine with chloramine‐ T have been studied in perchloric acid medium with palladous chloride as catalyst. The formation of {Pd(II)‐(aminoalcohol)} and {Pd(II)‐(aminoalcohol) 2 } complexes and resistance of {Pd(II)‐(aminoalcohol) 2 } complex to react with chloramine‐ T have been observed. A suitable mechanism consistent with the kinetic data is proposed and discussed.