Rate constant and products of the BrO + BrO reaction at 298 K | Zendy

Lançar I. T. | Zendy; Laverdet G. | Zendy; Bras G. Le | Zendy; Poulet G. | Zendy

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Rate constant and products of the BrO + BrO reaction at 298 K

Author(s) -

Lançar I. T.,

Laverdet G.,

Bras G. Le,

Poulet G.

Publication year - 1991

Publication title -

international journal of chemical kinetics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.341

H-Index - 68

eISSN - 1097-4601

pISSN - 0538-8066

DOI - 10.1002/kin.550230105

Subject(s) - chemistry , radical , reaction rate constant , mass spectrometry , analytical chemistry (journal) , constant (computer programming) , molecule , organic chemistry , kinetics , chromatography , computer science , programming language , physics , quantum mechanics

The overall rate coefficient k of the self recombination of BrO radicals has been measured at 298 K with use of the discharge flow/mass spectrometry technique. The rate coefficient k 2 for the reaction channel forming Br 2 has been also determined. The results are: k = (3.2 ± 0.5) × 10 −12 and k 2 = (4.7 ± 1.5) × 10 −13 (in cm 3 molecule −1 s −1 ). These results are discussed with respect to previous literature data.

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