Room temperature rate coefficient for the reaction between CH 3 O 2  and NO 3 | Zendy

Crowley J. N. | Zendy; Burrows J. P. | Zendy; Moortgat G. K. | Zendy; Poulet G. | Zendy; LeBras G. | Zendy

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Room temperature rate coefficient for the reaction between CH 3 O 2 and NO 3

Author(s) -

Crowley J. N.,

Burrows J. P.,

Moortgat G. K.,

Poulet G.,

LeBras G.

Publication year - 1990

Publication title -

international journal of chemical kinetics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.341

H-Index - 68

eISSN - 1097-4601

pISSN - 0538-8066

DOI - 10.1002/kin.550220703

Subject(s) - chemistry , photodissociation , kinetics , radical , analytical chemistry (journal) , molecule , photochemistry , organic chemistry , physics , quantum mechanics

The molecular modulation spectroscopic technique was employed to study the kinetics of NO 3 radicals produced in the 253.7 nm photolysis of flowing gas mixtures of HNO 3 /CH 4 /O 2 at room temperature. By computer fitting of the NO 3 temporal behavior, a rate coefficient of (2.3 ± 0.7) × 10 −12 cm 3 molecule −1 s −1 was obtained for the reaction between NO 3 and CH 3 O 2 at 298 K.

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