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Selectivity–reactivity correlations for thermal Diels–Alder reactions of cyclohexa‐1,3‐diene with substituted Ethenes in the gas phase
Author(s) -
Van Mele B.,
Huybrechts G.
Publication year - 1989
Publication title -
international journal of chemical kinetics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.341
H-Index - 68
eISSN - 1097-4601
pISSN - 0538-8066
DOI - 10.1002/kin.550211008
Subject(s) - chemistry , diene , reactivity (psychology) , selectivity , gas phase , diels–alder reaction , organic chemistry , medicinal chemistry , catalysis , medicine , natural rubber , alternative medicine , pathology
Selectivity–reactivity correlations are shown to support a biradical pathway for the gas phase thermal Diels–Alder reactions of cyclohexa‐1,3‐diene with substituted ethenes except for those involving a carbonyl group.