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The pressure and temperature dependence of methane decomposition
Author(s) -
Stewart P. H.,
Smith G. P.,
Golden D. M.
Publication year - 1989
Publication title -
international journal of chemical kinetics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.341
H-Index - 68
eISSN - 1097-4601
pISSN - 0538-8066
DOI - 10.1002/kin.550211005
Subject(s) - chemistry , methane , reaction rate constant , thermodynamics , decomposition , computational chemistry , kinetics , organic chemistry , quantum mechanics , physics
Single‐channel hindered Gorin model RRKM calculations were performed on reaction (1).Good agreement between theory and experiment was obtained for the temperature and pressure dependence of reaction (1). Isotopic data for the reverse association reaction, (−1), reported previously, are consistent with the model. Rate constants were cast in the form of an analytical expression and appropriate parameters were tabulated.