Kinetic study of the recombination reaction OD + NO 2  + M → DNO 3  + M | Zendy

Bossard Alain R. | Zendy; Singleton Donald L. | Zendy; Paraskevopoulos George | Zendy

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Kinetic study of the recombination reaction OD + NO 2 + M → DNO 3 + M

Author(s) -

Bossard Alain R.,

Singleton Donald L.,

Paraskevopoulos George

Publication year - 1988

Publication title -

international journal of chemical kinetics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.341

H-Index - 68

eISSN - 1097-4601

pISSN - 0538-8066

DOI - 10.1002/kin.550200803

Subject(s) - chemistry , torr , reaction rate constant , recombination , radical , kinetic energy , photodissociation , recombination rate , resonance (particle physics) , analytical chemistry (journal) , atomic physics , photochemistry , kinetics , thermodynamics , physics , organic chemistry , biochemistry , quantum mechanics , gene

Rate constants for the recombination reaction OD + NO 2 + M → DNO 3 + M have been determined in the falloff region (5–500 torr) and at 297 ± 2 K, in the presence of He, N 2 , and SF 6 as third bodies, by using a pulsed laser photolysis‐resonance absorption technique. Values of k 0 , k x and the falloff parameter F c have been estimated. Our rate constants were, within the experimental uncertainty, the same as those reported for the reaction of OH radicals with NO 2 .

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