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Kinetics of the gas‐phase thermal elimination of (β‐bromo ethyl)‐pyrazole
Author(s) -
Perez Jorge Daniel,
Phagouapé Leonardo Miguel
Publication year - 1988
Publication title -
international journal of chemical kinetics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.341
H-Index - 68
eISSN - 1097-4601
pISSN - 0538-8066
DOI - 10.1002/kin.550200802
Subject(s) - pyrazole , chemistry , kinetics , gas phase , bromide , pyrolysis , vinyl bromide , organic chemistry , computational chemistry , quantum mechanics , physics
Pyrazole elimination and vinyl bromide were found as products in the Flash Vacuum Pyrolysis of (β‐Bromo ethyl)‐pyrazole. To obtain kinetic parameters ( E a ) we carried out competitive reactions using (β‐chloro ethyl)‐pyrazole as an internal standard. A thermochemical study to calculate Δ(ΔH ƒ ∘) for this reaction was carried out.