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The kinetics of oxirane reaction with alkanethiols in the presence of basic catalysts
Author(s) -
Chlebicki Jan,
Cichacz Zbigniew
Publication year - 1988
Publication title -
international journal of chemical kinetics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.341
H-Index - 68
eISSN - 1097-4601
pISSN - 0538-8066
DOI - 10.1002/kin.550200505
Subject(s) - chemistry , catalysis , kinetics , reaction rate constant , kinetic energy , reaction mechanism , rate equation , atmospheric temperature range , mechanism (biology) , chemical kinetics , computational chemistry , reaction rate , photochemistry , thermodynamics , organic chemistry , philosophy , physics , epistemology , quantum mechanics
Rate constants for the reactions of oxirane with alkanethiols in the presence of basic catalyst were studied at the temperature range of 20–50°C. A mechanism of these reactions has been proposed and appropriate kinetic equation has been presented.