Kinetics, mechanism, and stereochemistry of Diels‐Alder reactions of carbonyl‐substituted ethenes with cyclohexa‐1,3‐diene in the gas phase | Zendy

Van Mele B. | Zendy; Tybaert C. | Zendy; Huybrechts G. | Zendy

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Kinetics, mechanism, and stereochemistry of Diels‐Alder reactions of carbonyl‐substituted ethenes with cyclohexa‐1,3‐diene in the gas phase

Author(s) -

Van Mele B.,

Tybaert C.,

Huybrechts G.

Publication year - 1987

Publication title -

international journal of chemical kinetics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.341

H-Index - 68

eISSN - 1097-4601

pISSN - 0538-8066

DOI - 10.1002/kin.550191203

Subject(s) - chemistry , diene , kinetics , gas phase , diels–alder reaction , stereochemistry , reaction mechanism , medicinal chemistry , organic chemistry , catalysis , physics , natural rubber , quantum mechanics

The kinetics of the Diels–Alder additions of CH 2 CHCHO, CH 2 C(CH 3 )CHO, and CH 2 CHC(CH 3 )O to cyclohexa‐1,3‐diene (CHD) have been studied in the gas phase. The stereochemistry and the mechanism of these reactions are discussed. In contrast with other Diels–Alder additions involving CHD as diene, a biradical mechanism does not fit the experimental results.

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