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The kinetics of oxiranes addition to bis/2‐hydroxyalkyl/disulfides and bis/2‐hydroxyalkyl/sulfides in the presence of N , N ‐dimethylcyclohexylamine
Author(s) -
Wilk Kazimiera A.,
Sokołowski Adam,
Burczyk Bogdan,
Chlebicki Jan
Publication year - 1987
Publication title -
international journal of chemical kinetics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.341
H-Index - 68
eISSN - 1097-4601
pISSN - 0538-8066
DOI - 10.1002/kin.550190704
Subject(s) - chemistry , kinetics , reaction rate constant , medicinal chemistry , kinetic energy , reaction mechanism , organic chemistry , catalysis , physics , quantum mechanics
Rate constants for the reaction of oxiranes with bis/2‐hydroxyalkyl/disulfides, bis/2‐Hydroxyalkyl/sulfides, and 1,6‐Hexanediol in the presence of N,N ‐dimethylcyclohexylamine were studied at the temperature range of 50–90°C. A mechanism of these reactions has been proposed and its kinetic equation has been presented.