The kinetics of oxiranes addition to bis/2‐hydroxyalkyl/disulfides and bis/2‐hydroxyalkyl/sulfides in the presence of  N , N ‐dimethylcyclohexylamine | Zendy

Wilk Kazimiera A. | Zendy; Sokołowski Adam | Zendy; Burczyk Bogdan | Zendy; Chlebicki Jan | Zendy

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The kinetics of oxiranes addition to bis/2‐hydroxyalkyl/disulfides and bis/2‐hydroxyalkyl/sulfides in the presence of N , N ‐dimethylcyclohexylamine

Author(s) -

Wilk Kazimiera A.,

Sokołowski Adam,

Burczyk Bogdan,

Chlebicki Jan

Publication year - 1987

Publication title -

international journal of chemical kinetics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.341

H-Index - 68

eISSN - 1097-4601

pISSN - 0538-8066

DOI - 10.1002/kin.550190704

Subject(s) - chemistry , kinetics , reaction rate constant , medicinal chemistry , kinetic energy , reaction mechanism , organic chemistry , catalysis , physics , quantum mechanics

Rate constants for the reaction of oxiranes with bis/2‐hydroxyalkyl/disulfides, bis/2‐Hydroxyalkyl/sulfides, and 1,6‐Hexanediol in the presence of N,N ‐dimethylcyclohexylamine were studied at the temperature range of 50–90°C. A mechanism of these reactions has been proposed and its kinetic equation has been presented.

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