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Temperature dependence of the quasiclassical reactivity for vibrationally excited hydrogen molecules colliding with hydrogen atoms
Author(s) -
Laganà A.
Publication year - 1986
Publication title -
international journal of chemical kinetics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.341
H-Index - 68
eISSN - 1097-4601
pISSN - 0538-8066
DOI - 10.1002/kin.550180910
Subject(s) - chemistry , reaction rate constant , excited state , hydrogen , hydrogen atom , atomic physics , range (aeronautics) , molecule , reactivity (psychology) , atmospheric temperature range , hydrogen molecule , parametrization (atmospheric modeling) , atom (system on chip) , kinetics , thermodynamics , physics , quantum mechanics , group (periodic table) , medicine , alternative medicine , organic chemistry , pathology , materials science , computer science , composite material , embedded system , radiative transfer
A discussion of reactants vibrational energy and temperature dependence of reactive rate constants for the hydrogen atom hydrogen molecule reaction is presented for a matrix of values calculated at 0 < v <10 and temperatures in the range from 300 K to 4000 K. A parametrization ofthe results is attempted. A comparison with rate constant values obtained from an approximate quantum treatment is also reported.