Kinetics and mechanism of the pyrolysis of 1‐Chloro‐1, 1‐difluoroethane in the presence of chlorine | Zendy

Huybrechts G. | Zendy; Hubin Y. | Zendy

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Kinetics and mechanism of the pyrolysis of 1‐Chloro‐1, 1‐difluoroethane in the presence of chlorine

Author(s) -

Huybrechts G.,

Hubin Y.

Publication year - 1986

Publication title -

international journal of chemical kinetics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.341

H-Index - 68

eISSN - 1097-4601

pISSN - 0538-8066

DOI - 10.1002/kin.550180408

Subject(s) - chemistry , arrhenius equation , chlorine , kinetics , thermal decomposition , decomposition , chlorine atom , pyrolysis , reaction rate constant , rate equation , reaction mechanism , mechanism (biology) , photochemistry , computational chemistry , thermodynamics , medicinal chemistry , organic chemistry , activation energy , catalysis , philosophy , physics , epistemology , quantum mechanics

The first stage thermal reactions of CF 2 CICH 3 in the presence of chlorine have been studied between 554 and 614 K. These areand\documentclass{article}\pagestyle{empty}\begin{document}$$ {\rm CF}_{\rm 2} {\rm CICH}_{\rm 3} {\rm + CI}_{\rm 2} \to {\rm CF}_{\rm 2} {\rm CICH}_{\rm 2} {\rm CI + HCI} $$\end{document}Rate equations derived from a radical mechanism are shown to fit the experimental results. Values of Arrhenius parameters for the decomposition of the CF 2 ClCH 2 . radical and its reactions with Cl 2 and Cl are given.

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