Premium
High‐pressure range of the recombination O + O 2 → O 3
Author(s) -
De Cobos A. E. Croce,
Troe J.
Publication year - 1984
Publication title -
international journal of chemical kinetics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.341
H-Index - 68
eISSN - 1097-4601
pISSN - 0538-8066
DOI - 10.1002/kin.550161206
Subject(s) - chemistry , extrapolation , flash photolysis , range (aeronautics) , analytical chemistry (journal) , atmospheric temperature range , flash (photography) , photodissociation , total pressure , recombination , reaction rate constant , thermodynamics , kinetics , photochemistry , optics , organic chemistry , mathematical analysis , biochemistry , physics , materials science , mathematics , quantum mechanics , gene , composite material
The recombination reaction O + O 2 → O 3 was studied by laser flash photolysis of pure O 2 in the pressure range 3–20 atm, and of N 2 OO 2 mixtures in the bath gases Ar, N 2 , (CO 2 , and SF 6 ) in the pressure range 3–200 atm. Fall‐off curves of the reaction have been derived. Low‐pressure rate coefficients were found to agree well with literature data. A high‐pressure rate coefficient of k ∞ = (2.8 ± 1.0) × 10 −12 cm 3 molecule −1 s −1 was obtained by extrapolation.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom