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Reactions of trichloromethyl radicals with organosilicon compounds
Author(s) -
Rice J. A.,
Treacy J. J.,
Sidebottom H. W.
Publication year - 1984
Publication title -
international journal of chemical kinetics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.341
H-Index - 68
eISSN - 1097-4601
pISSN - 0538-8066
DOI - 10.1002/kin.550161205
Subject(s) - organosilicon , chemistry , radical , arrhenius equation , photochemistry , hydrogen atom , hydrogen atom abstraction , carbon tetrachloride , photodissociation , hydrogen , cyclohexane , polar , organic chemistry , activation energy , alkyl , physics , astronomy
The photolysis of carbon tetrachloride in the presence of a number of organosilicon compounds has been investigated in the gas phase. The products obtained from the photolysis experiments were those expected from a chain reaction in which trichloromethyl radicals abstract hydrogen atoms from the organosilane. Arrhenius parameters for hydrogen atom transfer were determined relative to those for trichloromethyl radical combination.The activation energies for the reaction of methyl, trifluoromethyl, and trichloromethyl radicals with organosilicon compounds are compared and the results rationalized in terms of polar effects.