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The gas‐phase decomposition of methylsilane. Part I. Mechanism of decomposition under shock‐tube conditions
Author(s) -
Sawrey B. A.,
O'Neal H. E.,
Ring M. A.,
Coffey D.
Publication year - 1984
Publication title -
international journal of chemical kinetics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.341
H-Index - 68
eISSN - 1097-4601
pISSN - 0538-8066
DOI - 10.1002/kin.550160104
Subject(s) - chemistry , acetylene , shock tube , dimethylsilane , decomposition , gas phase , thermal decomposition , torr , analytical chemistry (journal) , organic chemistry , thermodynamics , shock wave , physics
The gas‐phase decompositions of methylsilane and methylsilane‐ d 3 have been investigated in a single‐pulse shock tube at 4700 torr total pressure in the temperature range of 1125–1250 K. For CH 3 SiD 3 at 1200 K three primary steps occur in the homogeneous decomposition with efficiencies in parentheses:\documentclass{article}\pagestyle{empty}\begin{document}$$ {\rm CH}_{\rm 3} {\rm SiD}_{\rm 3} \mathop {\longrightarrow} \limits^1 {\rm CH}_{\rm 3} {\rm SiD} + {\rm D}_{\rm 2} \left( {0.71} \right) $$\end{document} ,\documentclass{article}\pagestyle{empty}\begin{document}$$ {\rm CH}_{\rm 3} {\rm SiD}_{\rm 3} \mathop {\longrightarrow} \limits^2 {\rm CH}_{\rm 4} + {\rm SiD}_{\rm 2} \left( {0.15} \right) $$\end{document} , and\documentclass{article}\pagestyle{empty}\begin{document}$$ {\rm CH}_{\rm 3} {\rm SiD}_{\rm 3} \mathop {\longrightarrow} \limits^3 {\rm CH}_{\rm 2} \raise1pt\hbox{=\kern-3.45 pt=} {\rm SiD}_{\rm 2} \left( {0.14} \right) $$\end{document} . For CH 3 SiH 3 at 1200 K the primary CH 4 elimination efficiency is 0.09 while the total primary H 2 elimination efficiency is 0.91. Minor product formations of C 2 H 4 , acetylene, dimethylsilane, and SiH 4 are discussed.