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The kinetics and mechanisms of elementary NF 2 reactions with O and N atoms
Author(s) -
Gershenzon Yu. M.,
Il'in S. D.,
Kishkovitch O. P.,
Malkhasyan R. T.,
Rozenshtein V. B.,
Umanskii S. Ya.
Publication year - 1983
Publication title -
international journal of chemical kinetics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.341
H-Index - 68
eISSN - 1097-4601
pISSN - 0538-8066
DOI - 10.1002/kin.550150502
Subject(s) - chemistry , kinetics , stoichiometry , reaction rate constant , chemical kinetics , electron paramagnetic resonance , analytical chemistry (journal) , computational chemistry , organic chemistry , nuclear magnetic resonance , physics , quantum mechanics
Abstract A combined EPR–LMR spectrometer with a fast‐flow system has been used to investigate the kinetics and mechanisms of NF 2 reactions with O and N atoms at 298 K. The overall rate constants of these reactions are: k 0 = (2.8 ± 0.4) × 10 −11 cm 3 /s and k N = (5.7 ± 0.8) × 10 −11 cm 3 /s. The stoichiometry of the reactions with respect to O, N, NF 2 , F, and NO has been determined. The statistical theory of bimolecular reactions has been used for interpretation of the results obtained.