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Kinetics of dialin thermolysis
Author(s) -
Allen D. T.,
Gavalas G. R.
Publication year - 1983
Publication title -
international journal of chemical kinetics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.341
H-Index - 68
eISSN - 1097-4601
pISSN - 0538-8066
DOI - 10.1002/kin.550150303
Subject(s) - chemistry , thermal decomposition , kinetics , thermodynamics , decomposition , reaction rate constant , kinetic energy , range (aeronautics) , atmospheric temperature range , thermal , pyrolysis , chain reaction , organic chemistry , photochemistry , physics , materials science , quantum mechanics , composite material
The liquid‐phase thermolysis of 1,2‐dihydronaphthalene was studied in a batch reactor in the range of 350–400°C. The measured product distributions were in good agreement with calculations based on a free‐radical scheme with rate constants estimated by thermochemical methods. The kinetic calculations were carried out by numerical integration and by the long‐chain approximation (LCA), which yielded a closed‐form solution.
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