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A flash photolysis resonance fluorescence investigation of the reaction OH + H 2 O 2 → HO 2 + H 2 O
Author(s) -
Kurylo Michael J.,
Murphy Jennifer L.,
Haller Geoffrey S.,
Cornett Kenneth D.
Publication year - 1982
Publication title -
international journal of chemical kinetics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.341
H-Index - 68
eISSN - 1097-4601
pISSN - 0538-8066
DOI - 10.1002/kin.550141008
Subject(s) - chemistry , flash photolysis , flash (photography) , reaction rate constant , resonance fluorescence , photodissociation , work (physics) , computation , fluorescence , reaction rate , resonance (particle physics) , photochemistry , set (abstract data type) , range (aeronautics) , thermodynamics , kinetics , optics , atomic physics , algorithm , organic chemistry , computer science , quantum mechanics , physics , programming language , materials science , composite material , catalysis
Abstract The flash photolysis resonance fluorescence technique has been used to measure the rate constant for the reactionover the temperature range of 250–370 K. The present results are in excellent agreement with three very recent studies, and the combined data set can been used to derive the expressionsimilar to that currently used in atmospheric modeling applications. A summary of our computer simulation of this reaction system is presented. The results of the computations indicate the absence of secondary reaction complications in the present work while revealing significant problems in the earlier (pre‐1980) studies of the title reaction.