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Kinetics and mechanisms of oxidation of organic compounds by silver(II) species. Part VI: Iminodiacetic acid and N ‐methyliminodiacetic acid
Author(s) -
Baiocchi Claudio,
Bovio Giuseppe,
Mentasti Edoardo
Publication year - 1982
Publication title -
international journal of chemical kinetics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.341
H-Index - 68
eISSN - 1097-4601
pISSN - 0538-8066
DOI - 10.1002/kin.550140907
Subject(s) - chemistry , iminodiacetic acid , kinetics , oxidizing agent , inorganic chemistry , polyoxometalate , medicinal chemistry , organic chemistry , catalysis , chelation , physics , quantum mechanics
The kinetics and mechanism of oxidation of iminodiacetic acid and N ‐methyliminodiacetic acid by aquasilver(II) and Ag(II)‐2,2′‐bipyridine complexes has been investigated. The results are discussed with reference to the active reaction pathways, the equilibrium quotient of the title reactions, the protolytic equilibria which involve the oxidizing complex, and the intrinsic self‐exchange rates of the oxidants.