Basic hydrolysis of glyceryl nitrate esters. I. 1‐glyceryl and 2‐glyceryl nitrate esters | Zendy

Capellos C. | Zendy; Fisco W. J. | Zendy; Ribaudo C. | Zendy; Hogan V. D. | Zendy; Campisi J. | Zendy; Murphy F. X. | Zendy; Castorina T. C. | Zendy; Rosenblatt D. H. | Zendy

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Basic hydrolysis of glyceryl nitrate esters. I. 1‐glyceryl and 2‐glyceryl nitrate esters

Author(s) -

Capellos C.,

Fisco W. J.,

Ribaudo C.,

Hogan V. D.,

Campisi J.,

Murphy F. X.,

Castorina T. C.,

Rosenblatt D. H.

Publication year - 1982

Publication title -

international journal of chemical kinetics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.341

H-Index - 68

eISSN - 1097-4601

pISSN - 0538-8066

DOI - 10.1002/kin.550140809

Subject(s) - chemistry , hydrolysis , calcium hydroxide , aqueous solution , hydroxide , nitrate , organic chemistry , chromatography , inorganic chemistry

Kinetics of the basic hydrolysis of 1‐glyceryl mononitrate (1‐MNG) and 2‐glyceryl mononitrate (2‐MNG) were investigated in CO 2 ‐free aqueous calcium hydroxide solutions. The hydrolysis reactions were carried out in a temperature‐controlled reactor vessel with provision for continuous N 2 sparging of the reaction mixture. Both glyceryl nitrate esters hydrolyzed via second‐order reaction at 25°C. 2‐MNG in calcium hydroxide solution isomerized to 1‐MNG, which subsequently hydrolyzed to form NO 3 − . In strongly basic aqueous solutions of NaOH (30%), 2‐MNG is converted to glycidol and NO 3 − .

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