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Chemiluminescence simulation method for the evaluation of the termination rate constant for 2‐cyanopropyl peroxy and α‐phenyl‐ethyl peroxy radicals
Author(s) -
Lampert R.,
Phillips D.,
Vidoczy T.,
Lukacs J.,
Vasvari G.,
Gal D.
Publication year - 1982
Publication title -
international journal of chemical kinetics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.341
H-Index - 68
eISSN - 1097-4601
pISSN - 0538-8066
DOI - 10.1002/kin.550140606
Subject(s) - chemistry , azobisisobutyronitrile , chemiluminescence , ethylbenzene , radical , reaction rate constant , photochemistry , decomposition , analytical chemistry (journal) , organic chemistry , toluene , kinetics , polymerization , physics , quantum mechanics , polymer
An iterative method has been devised for the simulation of chemiluminescence data during the oxidative decomposition of αα′ azobisisobutyronitrile in the presence of ethylbenzene. From this simulation the cross termination rate constant of the two types of peroxy radicals present has been estimated.