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The reaction of O( 3 P ) with H 2 O 2
Author(s) -
Roscoe John M.
Publication year - 1982
Publication title -
international journal of chemical kinetics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.341
H-Index - 68
eISSN - 1097-4601
pISSN - 0538-8066
DOI - 10.1002/kin.550140504
Subject(s) - chemistry , reaction rate constant , constant (computer programming) , thermodynamics , function (biology) , reaction rate , mechanism (biology) , reaction mechanism , organic chemistry , kinetics , classical mechanics , catalysis , quantum mechanics , physics , evolutionary biology , computer science , biology , programming language
The rate constant for the reaction of O( 3 P ) with H 2 O 2 was measured as a function of temperature and the [H 2 O 2 ] 0 /[O] 0 ratio. The numerical solution of the appropriate rate equations was used to arrive at a mechanism which adequately describes our results and the rather divergent data in the literature. A recommended expression for the temperature dependence of the absolute rate constant is presented from consideration of the available experimental data.