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Kinetics and energetics of the criegee intermediate in the gas phase. II. The criegee intermediate in the photooxidation of formaldehyde, in alkyldioxy disproportionation and O + oxoalkane addition reactions
Author(s) -
Herron John T.,
Martinez Richard I.,
Huie Robert E.
Publication year - 1982
Publication title -
international journal of chemical kinetics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.341
H-Index - 68
eISSN - 1097-4601
pISSN - 0538-8066
DOI - 10.1002/kin.550140303
Subject(s) - chemistry , disproportionation , formaldehyde , kinetics , energetics , gas phase , photochemistry , alkene , computational chemistry , organic chemistry , catalysis , thermodynamics , physics , quantum mechanics
The gas‐phase kinetics and energetics of the Criegee intermediate, deduced from studies of O 3 ‐alkene systems, suggest that a hydroxy‐substituted Criegee intermediate probably participates in the photooxidation of formaldehyde. In contradistinction, the existing evidence suggests that the Criegee intermediate and its isomers are probably not involved in alkyldioxy disproportionation reactions. In the case of O + oxoalkane addition reactions, the Criegee intermediate and its isomers are discussed in terms of a complex equilibrium: .